Abstract.
Recently, it has been proved that the addition of Ta and B as quinary
elements to the quaternary Fe-Ni-Co-Al alloy alters the thermoelastic
martensitic transformation and also leads to "giant" superelasticity of
up to 13.5% in the Fe40.95Ni28Co17Al11.5Ta2.5B0.05
alloy. This is significantly larger than the best binary Ti-Ni shape memory
alloy. In addition, the iron-based shape memory alloy is 50% stronger than titanium
nickelide (YS =1 GPa). The ingots of alloys of Fe-Ni-Co-Al and Fe-Ni-Co-Al-Ta-B
were produced by induction melting/ arc melting technique followed by
homogenization annealing and quenching. Then the alloy ingots cut by electro-discharge
machining were further subjected to rolling. The crystal structure (by XRD)
and thermomechanical and magnetic properties were studied. The alloy exhibits
superelasticity at a temperature lower than 330 K. While measuring the
temperature dependence of magnetization, a behavior that is typical of ferromagnets
was observed. With a decrease in temperature from 335 K to 4 K, this behavior is
replaced by ambiguous hysteresis behavior. The data obtained can be explained
by a combination of states of the spin and strain-glass. Studies of
iron-containing alloys should be continued since strong superelasticity is of
great interest for the construction of superstructures that are resistant to
extreme loads.
Keywords:
phase transition, shape memory effect, superelasticity, strain glass,
spin glass, Fe-Ni-Co-Al-Ta-B, superstructures.
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