Journal of Radio Electronics. eISSN 1684-1719. 2025. ¹6
Full text in Russian (pdf)
DOI: https://doi.org/10.30898/1684-1719.2025.6.5
The effect of Ar and CO2 gas mixture composition
during sputtering of (Ba,Sr,Ca)CO3 films
on surface roughness and emission properties
G.A. Zhabin 1, Â.A. Loginov 2, A.B. Loginov 3, K.V. Shichalin 4
1 JSC «RPC «Istok» named after Shokin»
2a Vokzalnaya str., Fryazino, Moscow region, 141190
2 National Research University of ElectronicTechnology MIET
Shokin square 1, Moscow, Zelenograd, 124498
3 Lomonosov Moscow State University, Physical department
1 Leninskie Gory, Moscow, 119991
4 EPOS-Engineering,
1 Akademika Lavrentieva Ave., Novosibirsk, 630090
The paper was received March 6, 2025.
Abstract. The paper studies the influence of the composition of the Ar+CO2 gas mixture on the change in the chemical composition and morphology of emission coatings deposited using the ion-plasma method at a substrate holder temperature of 150-208 ºÑ. The grain size and surface roughness of the film are studied using scanning probe microscopy. The chemical composition of the deposited (Ba,Sr,Ca)CO3 films is studied using energy-dispersive X-ray analysis (EDXA). As the concentration of carbon dioxide in the gas mixture increases, the film grains enlarge to 1980 nm and lengthen, revealing an internal core nanostructure with an average transverse size of nanograins up to 181 nm. The influence of the gas composition on the deposition process and emission properties of molecularly sputter-deposited oxide microcathodes is shown.
Key words: ion plasma sputtering, scanning probe microscopy, surface morphology, emission characteristics, sputter-deposited oxide microcathodes, service life.
Corresponding author: Zhabin Gennady Anatolyevich, zhabingennady@yandex.ru
References
1. Lobanov V.M. et al. Field electron spectroscopy of a molecular-sprayed oxide thermocathode. // Journal of Radio Electronics. – 2024. – ¹. 9. https://doi.org/10.30898/1684-1719.2024.9.8 (In Russian).
2. Zhabin G.A., Ivanenko I.P. Durability of molecular sputter-deposited oxide cathodes in cyclotron protective devices. // Applied Physics. – 2020. –¹. 6. – P. 73 – 79. (In Russian).
3. Zhabin G.A., Arkhipov D.YU., Sedlovets D.M., Temiryazeva M.P. Parameters of ion-plasma deposition of oxide coatings and emission properties of sputter-deposited cathodes. // Ehlektronnaya tekhnika. Ser. 1. SVCH – tekhnika. – 2020. – V. 1 (544). – P. 46-55. (In Russian).
4. Kapustin V.I., Li I.P., Shumanov A.V. et al. Theory of Thermionic Emission of Scandate Cathodes. Tech. Phys. 65, 151–160 (2020). https://doi.org/10.1134/S1063784220010107.
5. Loginov B.A. et al. Observation of changes in the morphology of high-temperature metal films in a scanning probe microscope during warming up in open space conditions //Nanoindustry. – 2024. – V. 17. – ¹. 2. – P. 90-97. DOI: https://doi.org/10.22184/1993-8578.2024.17.2.90.97.
6. Kapustin V.I. et al. Technology of synthesis and electronic structure of triple barium–strontium–calcium carbonates for cathodes of microwave devices. Russ. Technol. J. – 2022. –V. 10(6). – P. 60-69. DOI: https: doi.org/10.32362/2500-316X-2022-10-6-60-6910(6)60−69.
7. Lobanov V.M. et al. Features of emission and field electron spectroscopy of oxide thermocathode. //Journal of Radio Electronics. – 2023.– ¹4. https://doi.org/10.30898/1684-1719.2023.4.6 (In Russian).
8. Tumarkin, A.V., Razumov, S.V., Volpyas, V.A. et al. Thermostable ferroelectric capacitors based on graded films of barium strontium titanate. Tech. Phys. 62, 1592–1598 (2017). https://doi.org/10.1134/S1063784217100231.
9. Thornton, J. A. Influence of apparatus geometry and deposition conditions on the structure and topography of thick sputtered coatings / J. A. Thornton // Journal of Vacuum Science & Technology. – 1974. – V. 11. – ¹ 4. – P. 666 – 670. https://doi.org/10.1116/1.1312732.
10. Thornton, J. A. The microstructure of sputter- deposited coatings / J. A. Thornton // Journal of Vacuum Science & Technology. A. – 1986, 4(6). – P. 3059 – 3065. doi: https://doi.org/10.1116/1.573628.
11. Mahieu, S., Ghekiere, P., Depla, D., De Gryse, R. Biaxial alignment in sputter deposited thin films / S. Mahieu, P. Ghekiere, D. Depla, R. De Gryse // Thin solid films. – 2006, 515. – P. 1229 – 1249. DOI: https://doi.org/10.1016/J.TSF.2006.06.027.
12. Zhabin G.A., Pelipets O.V., Sharapov N.A. The effect of magnetron sputtering conditions during deposition of (BaSrCa)CO3 coatings on thermionic emission of film microcathodes. Technical Physics Letters, 2024, Vol. 50, No. 6, P.34-37. https: doi.org/10.61011/PJTF.2024.11.57909.19827.
For citation:
Zhabin G.A., Loginov B.A., Loginov A.B., Shichalin K.V. The effect of Ar and CO2 gas mixture composition during sputtering of (Ba,Sr,Ca)CO3 films on surface roughness and emission properties // Journal of Radio Electronics. – 2025. – ¹6. https://doi.org/10.30898/1684-1719.2025.6.5 (In Russian)