Journal of Radio Electronics. eISSN 1684-1719. 2023. ¹11
ContentsFull text in Russian (pdf)
DOI: https://doi.org/10.30898/1684-1719.2023.11.18
APPLICATION OF THREE-LEVEL DISCRETIZATION METHOD
FOR ANALYSIS CONNECTION
BETWEEN STRUCTURE AND SPECIFIC CONDUCTIVITY OF GRAPHENE-CONTAINED SHUNGITE
I.V. Antonets1, E.A. Golubev2, V.G. Shavrov3, V.I. Shcheglov3
1 Syktyvkar State University, Syktyvkar, Russia
2 Geology Institute Komy SC UrD RAS, Syktyvkar, Russia
3 Institute of Radioengineering and Electronics RAS, Moscow, Russia
The paper was received November 28, 2023
Abstract. The correlation between structure configuration of carbon distribution of graphene-contained shungite and its specific electrical conductivity is investigated. The four shungite specimens from different natural depositions are investigated. The carbon structure configuration is investigated by high-permission raster electron microscopy. As a result, there was found cards of graphene layers, graphene packets and graphene ribbons along the plane of specimen surface. The specific electrical conductivity was merit be the four-contact method. On each specimen was found five cards in different its points as a whole – twenty cards. For the analysis of carbon local distribution, the descretization by three levels method was used. This method consists of applying on the card plane the grid with square cells and following analysis of regularity graphene layers by each cell. It is found three levels of order regularity structure: high, middle and low which distinguished by the number and length of graphene layers inside of cell. By averaging along all cards of present specimen for each specimen was found the own numerical characteristic which describes the carbon distribution structure. As a most important parameters were selected the averaged meaning of order degree and inversed value of square deflection from this value. It was found that the dependence of inverted value on specimen from the specimen number has the same character as the dependence on specific conductivity form the same number. As a result of investigations, it was proposed that the specific conductivity of shungite specimen may be found from statistical analysis of carbon space distribution cards which are found by the high-permission raster electron microscopy. It was proposed the algorithm of founding conductivity by analysis carbon configuration cards consisted from 16 successive steps which started from the founding the total combination of cards with the aid of electron microscope and finished by obtaining the electric conductivity value.
Keywords: carbon, shungite, electro-conductivity.
Financing: The work was carried out within the framework of the state assignment of the V.A. Kotelnikov Institute of Radioengineering and Electronics of the Russian Academy of Sciences.
Corresponding author: Shcheglov Vladimir Ignatyevich, vshcheg@cplire.ru
References
1. Sokolov V.A., Kalinin Yu.K., Gukkiev E.F. (egitor). Shungiti – novoe uglerodistoe sirye [Shungites – new carbon raw material]. Petrozavodsk: Karelia. 1984. 176 p. (In Russian).
2. Melezhik V.A., Filippov M.M., Romashkin A.E. A giant paleoproterozoic deposit of shungite in NW Russia. // Ore Geology Reviews. 2004. V.24. P.135-154.
3. Borisov P.A. Karelskie shungite. [Karelian shungites]. Petrozavodsk: Karelia. 1956. (In Russian).
4. Philippov M.M. Shungiteonosnie porodi onegskoi structure. [Shungite-containing rocks of Onega structure]. Petrozavodsk: Karelian SC RAS. 2002. (In Russian).
5. Philippov M.M., Medvedev P.P., Romashkin A.E. O prirode shungitov Yuzhnoy Karelii. [About nature of South Karelia shungites] // Litologia i poleznie iskopaemie – Lithology and useful minerals. 1998. ¹3. P.323-332. (In Russian).
6. Golubev Ye.A., Antonets I.V., Shcheglov V.I. Model presentation of microstructure, electroconductivity and microwave properties of shungite. Syktivkar: SyktSU. 2017. (In Russian).
7. Rodionov V.V. Mehanizmi vzaimodeystviya SVCh izluchenia s nanostrukturirovannimi uglerodsodershashchimi materialami. [The mechanisms of interaction of VHF-radiation with nanostructused carbon-contained materials]. // Master-thesis. Kursk. 2014. (In Russian).
8. Moshnikov I.A., Kovalevsky V.V., Lazareva T.N., Petrov A.V. Ispolzovanie shungitovih porod v sozdanii padioekraniruyushchih kompozitsionnih materialov. [The shungite rocks employment in creation of radio-screening composite materials]. // Materials of conference “Geodynamics, magmatizm, sedimentogenes and minerageniya of north-west of Russia”. Petrozavodsk: Geilogical institute of KarSC RAS. 2007. P.272-274. (In Russian).
9. Linkov L.M., Makhmud M.Sh., Kryshtopova E.A. Ekrani elektromagnitnogo izluchenia na osnove poroshkoobraznogo shungite. [The electromagnetic radiation screens on basis of powder-like shungite] // Bulletin of Polotsk State university. Series C. Main sciences. Novopolotsk: PSU. 2012. ¹4. P.103-108. (In Russian).
10. Linkov L.M., Borbotko T.V., Kryshtopova E.A. The radio-absorption properties of nickel-containing powdery shungite. // Technical Physics Letters. 2009. V.35. ¹9. P.44-48. (In Russian).
11. Linkov L.M., Borbotko T.V., Kryshtopova E.A. Microwave and optic properties of multi-functional screens of electromagnetic radiation on the basis of powder-like shungite. // Book of papers of 4-th international conference “Modern methods and technologies of creation and processing of materials”. Belarus. Minsk. 2009. P.23-25.
12. Emelyanov S.G., Kuzmenko A.P., Rodionov V.V., Dobromyslov M.B. Mechanisms of microwave absorption in carbon compounds from shungite. // Journal of Nano- and Electronic Physics. 2013. V.5. ¹4. P.04023-1 04023-3.
13. Kuzmenko A.P., Rodionov V.V., Kharseev V.A. Hyperfullerene carbon nane structures as a powder fill for absorption of microwave radiation. // Nano-technology. 2013. ¹4. P.35-36. (In Russian).
14. Kuzmenko A.P., Rodionov V.V., Emelyanov S.G., Chervyakov L.M., Dobromyslov M.B. Microwave properties of carbon nanotubes grown by pyrolysis of ethanol on nickel catalyst. // Journal of Nano- and Electronic Physics. 2014. V.6. ¹3. P.03037-1 03037-2.
15. Boiprav O.V., Ayad H.A.E., Lynkov L.M. Radioshielding properties of nickel-containing activated carbon. // Technical Physics Letters. 2019. V.45. ¹12. P.635-637.
16. Savenkov G.G., Morozov V.A., Ukraintseva T.V., Kats V.M., Zegrya G.G., Ilyushin M.A. The effect of shungite additives on electric discharge in ammonium perchlorate. // Technical Physics Letters. 2019. V.45. ¹19. P.1001-1003.
17. Golubev Ye.A., Antonets I.V., Shcheglov V.I. Static and dynamic conductivity of nanostructured carbonaceous shungite geomaterials. // Materials Chemistry and Physics. 2019. V. 226. ¹3. P.195-203.
18. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Dynamic microwave conductivity of graphene-based shungite. // Technical Physics Letters. 2018. V.44. ¹5. P.371-373.
19. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. The investigation of conductivity of graphene-containing shungite by waveguide method. // Book of papers of International symposium “Perspective materials and technologies”. Vitsebsk. Bilarus. 2017. P.6-9.
20. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Dynamic conductivity of graphene-containing shungite in microwave region. // Book of papers of conference “Phase transitions, critical and nonlinear phenomena in condensed media”. Institute of Physics of Dagestan Scientific Centre RAS. Makhachala. 2017. P.432-436.
21. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Dynamic conductivity of graphene-containing shungite in microwave region. // Book of papers of XXV International conference «Electromagnetic field and materials». M.: NIU MEI. 2017. P.135-147. (In Russian).
22. Morosov S.V., Novoselov K.S., Geim A.K. Electron transport in graphene. // Phys. Usp. 2008. V.51. ¹7. P.744-748.
23. Hill E.W., Geim A.K., Novoselov K., Schedin F., Blake P. Graphene spin valve devices. // IEEE Trans. Magn. 2006. V.42. ¹10. P.2694-2696.
24. Golovanov O.A., Makeeva G.S., Rinkevich A.B. Interaction of terahertz electromagnetic waves with periodic gratings of graphene micro- and nanoribbons. // Technical Physics. The Russian Journal of Applied Physics. 2016. V.61. ¹2. P.274-282.
25.Makeeva G.S., Golovanov O.A. Mathematical simulation of electron-guided designs of thera-cycle frequency range on the basis of graphene and carbon nano-tubes. Penza. Publ.:PSU. 2018. (In Russian).
26. Castro Neto A.H., Guinea F., Peres N.M.R., Novoselov K.S., Geim A.K. The electronic properties of graphene. Rev.Mod.Phys. 2009. V.81. ¹1. P.109-162(54).
27. Kovalevsky V.V. Structure of carbon substance and extraction of shungite rocks. // Doctor-thesis. Petrozavodsk. 2007. (In Russian).
28. Sheka E.F., Golubev E.A. Technical graphene (reduced graphene oxide) and its natural analog (shungite). // Technical Physics. The Russian Journal of Applied Physics. 2016. V.61. ¹7. P.1032-1038.
29. Golubev E.A., Ulyashev V.V., Veligshanin A.A. Poristost I strukturnie parametry shungitov Karelii po dannim malouglovogo rasseyania sinhrotronnogo izlychenia I mikroskopii [Porosity and structure parameters of Karelian shungite by data of small-angle dispersion of synchrotron radiation and microscopy]. // Kristallografia – Crystallography. 2016. V.61. ¹1. P.74-85. (In Russian).
30. Goldstein D., Jakovits H. (ed.). Practical raster electron microscopy. M.: Nauka. 1978.
31. Stoyanov P.A. Electron microscope. // Physic encyclopedia. V.5. M.: Large Russian encyclopedia. 1998. P.574-578.
32. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Presentation of electrical conductivity of graphene-containing shungite on the basis of current tubes model. // Zhurnal Radioelectroniki – Journal of Radio Electronics. 2020. ¹3. Available at: http://jre.cplire.ru/jre/mar20/7/text.pdf (In Russian).
33. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Application of block-discretization method for analysis of electrical conductivity of graphene-containing shungite. // Zhurnal Radioelectroniki – Journal of Radio Electronics. 2021. ¹3. http://jre.cplire.ru/jre/mar21/3/text.pdf
34. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Investigation of electrical conductivity of graphene-contained shungite using the high-resolution scanning electron microscopy. // Zhurnal Radioelectroniki – Journal of Radio Electronics. 2021. ¹3. http://jre.cplire.ru/jre/mar21/9/text.pdf
35. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Application of de-composition method for calculation of electrical conductivity of shungite based on the electron-microscopic cards of carbon distribution. // Zhurnal Radioelectroniki – Journal of Radio Electronics. 2021. ¹3. http://jre.cplire.ru/jre/mar21/13/text.pdf
36. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Application of independent-channel method for investigation of electrical conductivity of graphene-containing shungite. // Zhurnal Radio electroniki – Journal of Radio Electronics. 2021. ¹7. http://jre.cplire.ru/jre/jun21/6/text.pdf
37. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. The influence of carbon component structure of graphene containing shungite on its electrical conductivity. // Zhurnal Radio electroniki – Journal of Radio Electronics. 2021. ¹8.
http://jre.cplire.ru/jre/aug18/8/text.pdf
38. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Investigation of structure and electrical properties of graphene-containing shungite by data of electro-force spectroscopy. Part 1. Concentration of carbon. // Zhurnal Radioelectroniki – Journal of Radio Electronics. 2018. ¹8. Available at: http://jre.cplire.ru/jre/aug18/5/text.pdf (In Russian).
39. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Investigation of structure and electrical properties of graphene-containing shungite by data of electro-force spectroscopy. Part 2. Discretization of structure. // Zhurnal Radioelectroniki – Journal of Radio Electronics. 2018. ¹8. Available at: http://jre.cplire.ru/jre/aug18/6/text.pdf (In Russian).
41. Antonets I.V., Golubev Ye.A., Shcheglov V.I. Application of the trinary discretization method for the structural analysis of natural disordered sp2 carbon // Fullerenes, Nanotubes and Carbon Nanostructures. 2023. https://doi.org/10.1080/1536383X.2023.2273416
42.Vorobyeva L.A. Theory and practices of chemical analysis of soils. M.: GEOS. 2006.
43. Antonets I.V., Kotov L.N., Nekipelov S.V., Shavrov V.G., Shcheglov V.I. Electrodynamics properties of thin metal films with different thickness and morphology of surface. // Journal of Communications Technology and Electronics. 2004. V.49. ¹10. P.1243-1250.
44. Antonets I.V., Kotov L.N., Shavrov V.G., Shcheglov V.I. Conducting and reflection properties of nano-meter thickness films from different metals. // Journal of Communications Technology and Electronics. 2006. V.51. ¹12. P.1481-1487.
For citation:
Antonets I.V., Golubev E.A., Shavrov V.G., Shchegliv V.I. Application of three-level discretization method for analysis connection between structure and specific conductivity of graphene-contained shungite // Journal of Radio Electronics. – 2023. – ¹. 11. https://doi.org/10.30898/1684-1719.2023.11.18 (In Russian)