Journal of Radio Electronics. eISSN 1684-1719. 2026. ¹8
Full text in Russian (pdf)
DOI: https://doi.org/10.30898/1684-1719.2026.8.11
Computer simulation
of electrical conductivity
in polymer composites with carbon filler
S.V. Belim
Omsk State Technical University,
644050, Russia, Omsk, pr. Mira, 11
The paper was received July 8, 2026.
Abstract. Conductive polymer composites with carbon filler are actively used in electronic devices for shielding various nodes. Carbon black is one of the cheapest materials used as a filler and provides electrical conductivity. The article examines electrical conductivity in polymer composite materials with carbon black filler by computer simulation. A new approach to the formation of carbon particles agglomerates based on the Monte Carlo method is proposed. Agglomerates have electrical conductivity due to their composition and structure. The simulation suggests two conduction mechanisms between the agglomerates. Electric current passes through direct contact between particles of agglomerates. A tunneling effect is also possible for electrons between neighbor agglomerates with a small distance between them. In the simulation, the maximum distance between the agglomerates is entered to ensure electrical conductivity. Based on the search for conductive contacts between the agglomerates, a graph corresponding to the electrical network formed by the agglomerates within the composite sample is inserted. The search for conducting paths is carried out using a graph clustering algorithm that reveals a subset of connected agglomerates. Systems with different concentrations of carbon black particles have been investigated. A dependence of the probability of the occurrence of electroconductive paths on the concentration of carbon black particles was obtained in computer experiment. It is shown that electrical percolation takes place in the system, transforming the composite from a dielectric state into a conductive one. Percolation transition occurs in the range of volume concentration from 5 % to 15 %. At volume concentrations of carbon particles above 15 %, conductive paths are formed with a probability of unity and the composite material becomes a conductor. The obtained values are in good agreement with the experimental data. The difference between the proposed model and the previously developed one is taking into account the structure, shape and spread of the agglomerate sizes. This refinement of the model will increase the agreement of the simulation results with the experimental data. The search for conductive paths based on the clustering algorithm gives not only the path length, but also allows you to take into account the change in the thickness of the agglomerates conductive chain.
Key words: conductivity of composites, computer simulation, Monte Carlo method.
Financing: The research was supported by a grant from the Russian Science Foundation No. 26-29-20003 and a grant ¹ 23 from the Omsk Region 08.07.2026
Corresponding author: Belim Sergey Victorovich, sbelim@mail.ru
References
1. Selvakumaran L., Lubineau G. Electrical behavior of laminated composites with intralaminar degradation: A comprehensive micro-meso homogenization procedure //Composite Structures. – 2014. – Ò. 109. – Ñ. 178-188. https://doi.org/10.1016/j.compstruct.2013.10.057
2. de Souza Vieira L. et al. Carbon-based materials as antistatic agents for the production of antistatic packaging: a review //Journal of Materials Science: Materials in Electronics. – 2021. – Ò. 32. – ¹. 4. – Ñ. 3929-3947. https://doi.org/10.1007/s10854-020-05178-6
3. Zhang W. et al. Advances in waterborne polymer/carbon material composites for electromagnetic interference shielding //Carbon. – 2021. – Ò. 177. – Ñ. 412-426. https://doi.org/10.1016/j.carbon.2021.02.093
4. Shakir M. F. et al. EMI shielding characteristics of electrically conductive polymer blends of PS/PANI in microwave and IR region: Shakir, Abdul Rashid, Tariq, Nawab, Afzal, Nabeel, Naseem, and Hamid //Journal of Electronic Materials. – 2020. – Ò. 49. – ¹. 3. – Ñ. 1660-1665. https://doi.org/10.1007/s11664-019-07631-7
5. Lyu L. et al. Extracting carrier mobility using a photoinduced charge transfer reaction: From conducting polymers to nanocarbon materials //Organic Electronics. – 2020. – Ò. 78. – Ñ. 105615. https://doi.org/10.1016/j.orgel.2020.105615
6. Gómez I. J. et al. Carbon nanomaterials embedded in conductive polymers: A state of the art //Polymers. – 2021. – Ò. 13. – ¹. 5. – Ñ. 745. https://doi.org/10.3390/polym13050745
7. Bertolini M. C. et al. Hybrid composites based on thermoplastic polyurethane with a mixture of carbon nanotubes and carbon black modified with polypyrrole for electromagnetic shielding //Frontiers in Materials. – 2020. – Ò. 7. – Ñ. 174. https://doi.org/10.3389/fmats.2020.00174
8. Zhao L., Xia W., Zhang P. Economical conductive graphite‐filled polymer composites via adjustable segregated structures: Construction, low percolation threshold, and positive temperature coefficient effect //Journal of Applied Polymer Science. – 2021. – Ò. 138. – ¹. 17. – Ñ. 50295. https://doi.org/10.1002/app.50295
9. Al-Saleh M. H., Sundararaj U. A review of vapor grown carbon nanofiber/polymer conductive composites //Carbon. – 2009. – Ò. 47. – ¹. 1. – Ñ. 2-22. https://doi.org/10.1016/j.carbon.2008.09.039
10. Wu J., Pisula W., Müllen K. Graphenes as potential material for electronics //Chemical reviews. – 2007. – Ò. 107. – ¹. 3. – Ñ. 718-747. https://doi.org/10.1021/cr068010r
11. Selvakumaran L., Lubineau G. Electrical behavior of laminated composites with intralaminar degradation: A comprehensive micro-meso homogenization procedure //Composite Structures. – 2014. – Ò. 109. – Ñ. 178-188. https://doi.org/10.1016/j.compstruct.2013.10.057
12. Lv Z. et al. Scalable manufacturing of conductive rubber nanocomposites with ultralow percolation threshold for strain sensing applications //Composites Communications. – 2021. – Ò. 25. – Ñ. 100685. https://doi.org/10.1016/j.coco.2021.100685
13. Sengun P. et al. Characterization of designed, transparent and conductive Al doped ZnO particles and their utilization in conductive polymer composites //Powder Technology. – 2020. – Ò. 374. – Ñ. 214-222. https://doi.org/10.1016/j.powtec.2020.07.025
14. Pawłowska M., Sikorski A. Monte carlo study of the percolation in two-dimensional polymer systems //Journal of Molecular Modeling. – 2013. – Ò. 19. – ¹. 10. – Ñ. 4251-4258. https://doi.org/10.1007/s00894-013-1892-y
15. Oh J. Y. et al. Enhanced electrical networks of stretchable conductors with small fraction of carbon nanotube/graphene hybrid fillers //ACS applied materials & interfaces. – 2016. – Ò. 8. – ¹. 5. – Ñ. 3319-3325. https://doi.org/10.1021/acsami.5b11205
16. Chanklin W., Laowongkotr J., Chibante L. P. F. Electrical property validation of percolation modeling in different polymer structures of carbon-based nanocomposites //Materials today Communications. – 2018. – Ò. 17. – Ñ. 153-160. https://doi.org/10.1016/j.mtcomm.2018.09.004
17. Tang Z. H. et al. Modeling the synergistic electrical percolation effect of carbon nanotube/graphene/polymer composites //Composites Science and Technology. – 2022. – Ò. 225. – Ñ. 109496. https://doi.org/10.1016/j.compscitech.2022.109496
18. Rahaman M. et al. A new insight in determining the percolation threshold of electrical conductivity for extrinsically conducting polymer composites through different sigmoidal models //Polymers. – 2017. – Ò. 9. – ¹. 10. – Ñ. 527. https://doi.org/10.3390/polym9100527
19. Feng C., Jiang L. Micromechanics modeling of the electrical conductivity of carbon nanotube (CNT)–polymer nanocomposites //Composites Part A: Applied Science and Manufacturing. – 2013. – Ò. 47. – Ñ. 143-149. https://doi.org/10.1016/j.compositesa.2012.12.008
20. Qu F. et al. Synergistic effect in improving the electrical conductivity in polymer nanocomposites by mixing spherical and rod-shaped fillers //Soft Matter. – 2020. – Ò. 16. – ¹. 46. – Ñ. 10454-10462. https://doi.org/10.1039/D0SM00993H
21. Wang Y. et al. Microstructural modeling and simulation of a carbon black-based conductive polymer─ a template for the virtual Design of a Composite Material //ACS omega. – 2022. – Ò. 7. – ¹. 33. – Ñ. 28820-28830. https://doi.org/10.1021/acsomega.2c01755
22. Azizi S. et al. Electrical and thermal phenomena in low‐density polyethylene/carbon black composites near the percolation threshold //Journal of Applied Polymer Science. – 2019. – Ò. 136. – ¹. 6. – Ñ. 47043. https://doi.org/10.1002/app.47043
23. Li F. et al. Polyurethane/conducting carbon black composites: structure, electric conductivity, strain recovery behavior, and their relationships //Journal of Applied Polymer Science. – 2000. – Ò. 75. – ¹. 1. – Ñ. 68-77. https://doi.org/10.1002/(SICI)1097-4628(20000103)75:1<68::AID-APP8>3.0.CO;2-I
24. Cruz S. M., Viana J. C. Melt blending and characterization of carbon nanoparticles-filled thermoplastic polyurethane elastomers //Journal of Elastomers & Plastics. – 2015. – Ò. 47. – ¹. 7. – Ñ. 647-665. https://doi.org/10.1177/0095244314534097
25. Vas J. V., Joy Thomas M. Monte Carlo modelling of percolation and conductivity in carbon filled polymer nanocomposites //IET Science, Measurement & Technology. – 2018. – Ò. 12. – ¹. 1. – Ñ. 98-105. https://doi.org/10.1049/iet-smt.2017.0093
26. Arun D. I. et al. Experimental and Monte Carlo simulation studies on percolation behaviour of a shape memory polyurethane carbon black nanocomposite //Smart Materials and Structures. – 2019. – Ò. 28. – ¹. 5. – Ñ. 055010. https://doi.org/10.1088/1361-665X/ab083b
27. Ji J. et al. A simulation for the electrical conductivity of nanocomposites filled with carbon black based on the three-dimensional Monte Carlo method //Polymer Science, Series A. – 2021. – Ò. 63. – ¹. 2. – Ñ. 196-207. https://doi.org/10.1134/S0965545X21020048
28. Coupette F. et al. Percolation of rigid fractal carbon black aggregates //The Journal of Chemical Physics. – 2021. – Ò. 155. – ¹. 12. https://doi.org/10.1063/5.0058503
29. Zhu X. et al. A study of the appropriateness, geometry, size, and fillers boundary restraint on representative volume element in electrical simulation for carbon-based nanocomposites //Materials Today Communications. – 2020. – Ò. 25. – Ñ. 101639. https://doi.org/10.1016/j.mtcomm.2020.101639
30. Mazaheri M., Payandehpeyman J., Jamasb S. Modeling of effective electrical conductivity and percolation behavior in conductive-polymer nanocomposites reinforced with spherical carbon black //Applied Composite Materials. – 2022. – Ò. 29. – ¹. 2. – Ñ. 695-710. https://doi.org/10.1007/s10443-021-09991-y
31. Clingerman M. L. et al. Evaluation of electrical conductivity models for conductive polymer composites //Journal of Applied Polymer Science. – 2002. – Ò. 83. – ¹. 6. – Ñ. 1341-1356. https://doi.org/10.1002/app.10014
32. Min C. et al. The electrical properties and conducting mechanisms of carbon nanotube/polymer nanocomposites: A review //Polymer-Plastics Technology and Engineering. – 2010. – Ò. 49. – ¹. 12. – Ñ. 1172-1181. https://doi.org/10.1080/03602559.2010.496405
33. Simmons J. G. Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film //Journal of applied physics. – 1963. – Ò. 34. – ¹. 6. – Ñ. 1793-1803. https://doi.org/10.1063/1.1702682
34. Coupette F. et al. Percolation of rigid fractal carbon black aggregates //The Journal of Chemical Physics. – 2021. – Ò. 155. – ¹. 12. https://doi.org/10.1063/5.0058503
35. Landau D. P., Binder K. Phase diagrams and multicritical behavior of a three-dimensional anisotropic Heisenberg antiferromagnet //Physical Review B. – 1978. – Ò. 17. – ¹. 5. – Ñ. 2328. https://doi.org/10.1103/PhysRevB.17.2328
36. Stepashkina A. S. et al. Modeling electric conduction in composite materials based on polypropylene and carbon black //Technical Physics Letters. – 2015. – Ò. 41. – ¹. 1. – Ñ. 57-59. https://doi.org/10.1134/S1063785015010307
For citation:
Belim S.V. Computer simulation of electrical conductivity in polymer composites with carbon filler. // Journal of Radio Electronics. – 2026. – ¹ 8. https://doi.org/10.30898/1684-1719.2026.8.11 (In Russian)