Journal of Radio Electronics. eISSN 1684-1719. 2025. ¹11
Full text in Russian (pdf)
DOI: https://doi.org/10.30898/1684-1719.2025.11.41
APPLICATION OF RESISTIVE NET METHOD
FOR INVESTIGATING OF GRAPHENE CONTAINING
SHUNGITE CONDUCTIVITY
BY DATA OF ELECTRIC-FORCED MICROSCOPY METHOD
I.V. Antonets 1, E.A. Golubev 2, V.I. Shcheglov 3
1 Syktyvkar State University, Syktyvkar, Russia
2 Geology Institute Komy SC UrD RAS, Syktyvkar, Russia
3 Institute of Radio Engineering and Electronics RAS, Moscow, Russia
The paper was received September 23, 2025.
Abstract. The possibility of application resistive net method for analysis of graphene containing shungite resistance by data of electric-forced microscopy method is investigated. It is noted the task of shungite application for microwave radiation screen creating. It is described the example of carbon concentration content card by electric-forced microscopy method and its binomial discretization is carried out. It is described the scheme of resistive net construction on the basis of discreted card. It is carried out the rolling up procedure as a result of its the net is transformed into single resistor with nominal equal to resistance of whole net. It is described the scheme of receiving partial cards by cutting single card to four parts. It is found the dependencies of partial cards resistance from the quartz cell resistance. It is found two classes of these dependencies: increasing with saturation and increasing linear. It is found the “through channel” existence which is consisted of continuous chain from carbon cells. It is found that the increasing with saturation is dependents from existence the through channel on the partial card. It is found that when through channel is absent the dependence of card resistance from quartz cell resistance is increasing linear. It is carried out the normalization of different samples resistive nets from the conductivity measured by contact method. It is found the normalization coefficient which allows to receive the conductivity value in accuracy for 25 %. It is investigated the influence of sample nonuniformity to carrying measuring. It is proposed some recommendations for further development of investigations.
Keywords: graphene containing shungite, electric-forced microscopy, resistive net.
Financing: The study was carried out within the framework of the state order of FSBEI VO “Syktyvkar State University named after Pitirim Sorokin” ¹ 075-03-2024-162 on the topic “Influence of structure on static and dynamic conductive properties of disordered carbon” (the receiving of shungite cards by electric-forced microscopy method) and also the work was carried out within the framework of the state assignment of the V.A.Kotelnikov Institute of Radio Engineering and Electronics of the Russian Academy of Sciences (investigation of cards by resistive net method).
Corresponding author: Shcheglov Vladimir Ignatyevich, vshcheg@cplire.ru
References
1. Moshnikov I.A., Kovalevsky V.V., Lazareva T.N., Petrov A.V. Ispolzovanie shungitovih porod v sozdanii padioekraniruyushchih kompozitsionnih materialov. [The shungite rocks employment in creation of radio-screening composite materials]. // Materials of conference “Geodynamics, magmatizm, sedimentogenes and minerageniya of north-west of Russia”. Petrozavodsk: Geilogical institute of KarSC RAS. 2007. P.272-274. (In Russian)
2. Linkov L.M., Makhmud M.Sh., Kryshtopova E.A. Ekrani elektromagnitnogo izluchenia na osnove poroshkoobraznogo shungite. [The electromagnetic radiation screens on basis of powder-like shungite] // Bulletin of Polotsk State university. Series C. Main sciences. Novopolotsk: PSU. 2012. ¹4. P.103-108. (In Russian)
3. Linkov L.M., Borbotko T.V., Kryshtopova E.A. The radio-absorption properties of nickel-containing powdery shungite. // Technical Physics Letters. 2009. V.35. ¹9. P.44-48. (In Russian)
4. Linkov L.M., Borbotko T.V., Kryshtopova E.A. Microwave and optic properties of multi-functional screens of electromagnetic radiation on the basis of powder-like shungite. // Book of papers of 4-th international conference “Modern methods and technologies of creation and processing of materials”. Belarus. Minsk. 2009. P.23-25.
5. Emelyanov S.G., Kuzmenko A.P., Rodionov V.V., Dobromyslov M.B. Mechanisms of microwave absorption in carbon compounds from shungite. // Journal of Nano- and Electronic Physics. 2013. V.5. ¹4. P.04023-1 04023-3.
6. Kuzmenko A.P., Rodionov V.V., Emelyanov S.G., Chervyakov L.M., Dobromyslov M.B. Microwave properties of carbon nanotubes grown by pyrolysis of ethanol on nickel catalyst. // Journal of Nano- and Electronic Physics. 2014. V.6. ¹3. P.03037-1 03037-2.
7. Boiprav O.V., Ayad H.A.E., Lynkov L.M. Radioshielding properties of nickel-containing activated carbon. // Technical Physics Letters. 2019. V.45. ¹12. P.635-637. https://doi.org/10.21883/PJTF.2019.12.47921.17225
8. Savenkov G.G., Morozov V.A., Ukraintseva T.V., Kats V.M., Zegrya G.G., Ilyushin M.A. The effect of shungite additives on electric discharge in ammonium perchlorate. // Technical Physics Letters. 2019. V.45. ¹19. P.1001-1003. https://doi.org/10.21883/PJTF.2019.19.48318.17847
9. Golubev Ye.A., Antonets I.V., Shcheglov V.I. Model presentation of microstructure, electroconductivity and microwave properties of shungite. Syktivkar: SyktSU. 2017. (In Russian)
10. Makeeva G.S., Golovanov O.A. Mathematical modeling of electronics-controlled theracycle-microwave devices based on grapheme and carbon nano-tubes. Penza. Published by PSU. 2018.
11. Golubev Ye.A., Antonets I.V., Shcheglov V.I. Static and dynamic conductivity of nanostructured carbonaceous shungite geomaterials. // Materials Chemistry and Physics. 2019. V. 226. ¹3. P.195-203.
12. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Dynamic microwave conductivity of graphene-based shungite. // Technical Physics Letters. 2018. V.44. ¹5. P.371-373. https://doi.org/10.21883/PJTF.2018.09.46060.16883
13. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. The investigation of conductivity of graphene-containing shungite by waveguide method. // Book of papers of International symposium “Perspective materials and technologies”. Vitsebsk. Bilarus. 2017. P.6-9.
14. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Dynamic conductivity of graphene-containing shungite in microwave region. // Book of papers of XXV International conference «Electromagnetic field and materials». M.: NIU MEI. 2017. P.135-147. (In Russian)
15. Sokolov V.A., Kalinin Yu.K., Dukkiev E.F. (egitor). Shungiti – novoe uglerodistoe sirye [Shungites – new carbon raw material]. Petrozavodsk: Karelia. 1984. 176 p. (In Russian)
16. Melezhik V.A., Filippov M.M., Romashkin A.E. A giant paleoproterozoic deposit of shungite in NW Russia. // Ore Geology Reviews. 2004. V.24. P.135-154.
17. Philippov M.M., Medvedev P.P., Romashkin A.E. O prirode shungitov Yuzhnoy Karelii. [About nature of South Karelia shungites] // Litologia i poleznie iskopaemie – Lithology and useful minerals. 1998. ¹3. P.323-332. (In Russian)
18. Kovalevsky V.V. Structure of carbon substance and extraction of shungite rocks. // Doctor-thesis. Petrozavodsk. 2007. (In Russian)
19. Philippov M.M. Shungiteonosnie porodi onegskoi structure. [Shungite-containing rocks of Onega structure]. Petrozavodsk: Karelian SC RAS. 2002.
20. Sheka E.F., Golubev E.A. Technical graphene (reduced graphene oxide) and its natural analog (shungite). // Technical Physics. The Russian Journal of Applied Physics. 2016. V.61. ¹7. P.1032-1038.
21. Geim A.K. Random walk to graphene. // Physics Uspekhi. 2011. V.54. ¹12. P.1284-1298. https://doi.org/10.3367/UFNr.0181.201112e.1284
22. Morosov S.V., Novoselov K.S., Geim A.K. Electron transport in graphene. // Phys. Usp. 2008. V.51. ¹7. P.744-748. https://doi.org/10.3367/UFNr.01788.2000807i8.0776
23. Hill E.W., Geim A.K., Novoselov K., Schedin F., Blake P. Graphene spin valve devices. // IEEE Trans. Magn. 2006. V.42. ¹10. P.2694-2696.
24. Castro Neto A.H., Guinea F., Peres N.M.R., Novoselov K.S., Geim A.K. The electronic properties of graphene. Rev.Mod.Phys. 2009. V.81. ¹1. P.109-162(54).
25. DeFord D.D. Electroanalysis and coulometric analysis. // Analytical Chemistry. 1960. V.32. ¹5. P.31R-37R. https://doi.org/10.1021/ac60161a604.
26. Kies H.I. Coulometry. // Journal of Electroanalytical Chemistry. 1962. V.4. ¹5. P.257-286. https://doi.org/10.1016/S0022-0728(62)80068-0.
27. Vorobyeva L.F. Theory and practice of soil chemical analysis.M.: GEOS. 2006.
28. Mironov V.L. The foundations of scan-probe-microscopy. Technosfera. 2005.
29. Banerjee S., Sardar M., Gayathri N., Tyagi A.K., Baldev Raj. Enhanced conductivity in grapheme layers and at their edges. // APL. 2006. V.88. ¹6. P.062111.
30. Golubev E.A. Electro-physical properties and structure peculiarities of shungite (natural nano-structured carbon). // Physics of Solid State. 2013. V.55. ¹5. P.995-1002.
31. Antonets I.V., Golubev Ye.A., Shavrov V.G., Shcheglov V.I. Structure and electric properties of graphene containing shungite on the basis of conductivity cards analysis. // Book of papers of XXVI international conference “Electromagnetic field and materials (fundamental physics investigations)”. M.: INFRA-M. 2018. P.293-302.
32. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Investigation of structure and electrical properties of graphene-containing shungite by data of electro-force spectroscopy. Part 1. Concentration of carbon. // Journal of Radio Electronics. – 2018. – ¹. 8. https://doi.org/10.30898/1684-1719.2018.8.5
33. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Investigation of structure and electrical properties of graphene-containing shungite by data of electro-force spectroscopy. Part 2. Discretization of structure. // Journal of Radio Electronics. – 2018. – ¹. 8. https://doi.org/10.30898/1684-1719.2018.8.6
34. Antonets I.V., Golubev E.A., Shavrov V.G., Shcheglov V.I. Investigation of structure and electrical properties of graphene-containing shungite by data of electro-force spectroscopy. Part 3. Integral conductivity. // Journal of Radio Electronics. – 2018. – ¹. 9. https://doi.org/10.30898/1684-1719.2018.9.1
35. Ilyin V.A., Poznyak E.G. Foundation of mathematical analysis. Part 1. M.: Nauka. 1965.
36. Demidovich B.P., Maron I.A. Foundations of computational mathematics. M.: Fizmatgiz. 1963.
37. Ionkin P.A., Melnikov N.A., Darevski A.I., Kukharkin E.S. Theoretic foundations of electrician engineering. Part 1. Foundations of circuits theory. M.: Higher education school. 1965.
38. Frank D.J., Lobb C.J. Highly efficient algorithm for percolative transport studies in two dimensions. // Phys. Rev.B. 1988. V.37. ¹1. P.302-307.
39. Bulavin L.A., Vigormitski N.V., Lebovka N.I. Computer simulation pf physical systems. Dolgoprunni. Publishing House “Intellect”. 2011.
40. Pyarnpuu A.A. Programmatic on Algol and Fortran. M.: Nauka. 1978.
For citation:
Antonets I.V., Golubev E.A., Shcheglov V.I. Application of resistive net method for investigating of graphene containing shungite conductivity by data of electric-forced microscopy method // Journal of Radio Electronics. – 2025. – ¹ 11. https://doi.org/10.30898/1684-1719.2025.11.41 (In Russian)