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Journal of Radio Electronics Online scientific journal · eISSN 1684-1719
2018, № 7 · SOLID STATE ELECTRONICS

Исследование структуры и физических свойств сплавов семейства Fe-Ni-Co-Al

V.V. Koledov1, E.T. Dilmieva1, V.S. Kalashnikov1, A.P. Kamantsev1, A.V. Mashirov1, S.V. Fon Gratovski1, V.G. Shavrov1, I.S. Koshkidko1,2, A.V. Koshelev3, S.V. Taskaev4, V. Sampat5, I.I. Musabirov6, F.V. Chung7, R.M. Grechishkin8

1 Kotelnikov IRE RAS, Moscow, Russia
2 Институт низких температур и структурных исследований ПАН, 50-422, Вроцлав, Польша, Poland
3 Московский государственный университет им. М.В. Ломоносова, 119991, Москва, Ленинские горы, д. 1, Russia
4 Челябинский государственный университет, 454001, Челябинск, ул. Братьев Кашириных, 129, Russia
5 Индийский технологический институт Мадраса, 600036, Ченнай, Индия, India
6 Институт проблем сверхпластичности металлов РАН, 450001, Уфа, ул. Степана Халтурина, 39, Russia
7 Московский физико-технический институт, 141701, Московская обл., Долгопрудный, Институтский пер., 9
8 Тверской государственный университет, 170100, Тверь, ул. Желябова, 33, Russia
Full text (PDF) DOI: 10.30898/1684-1719.2018.7.8 UDC 539.371, 538.911 EDN YABJXF

Abstract

Методами индукционной и дуговой плавки с последующим гомогенизирующим отжигом и закалкой изготовлены слитки сплавов систем Fe-Ni-Co-Al и Fe-Ni-Co-Al-Ta-B, затем электрорезкой и прокаткой изготовлены пластины сплавов и исследованы кристаллографическая структура методом рентгеновской дифракции, а также термомеханические и магнитные свойства. Показан эффект сверхупругости при температуре ниже 330 К. При измерении температурных зависимостей намагниченности обнаружен типичный для ферромагнетиков ход, который при понижении температуры от 335 К до 4 К сменяется неоднозначным гистерезисным поведением. Полученные данные можно объяснить комбинацией состояний «спинового» и «деформационного стекла». Исследования железосодержащих сплавов должны быть продолжены, представляют большой интерес для создания сверхустойчивых к экстремальным нагрузкам конструкций. Recently, it has been proved that the addition of Ta and B as quinary elements to the quaternary Fe-Ni-Co-Al alloy alters the thermoelastic martensitic transformation and also leads to "giant" superelasticity of up to 13.5% in the Fe40.95Ni28Co17Al11.5Ta2.5B0.05 alloy. This is significantly larger than the best binary Ti-Ni shape memory alloy. In addition, the iron-based shape memory alloy is 50% stronger than titanium nickelide (YS =1 GPa). The ingots of alloys of Fe-Ni-Co-Al and Fe-Ni-Co-Al-Ta-B were produced by induction melting/ arc melting technique followed by homogenization annealing and quenching. Then the alloy ingots cut by electro-discharge machining were further subjected to rolling. The crystal structure (by XRD) and thermomechanical and magnetic properties were studied. The alloy exhibits superelasticity at a temperature lower than 330 K. While measuring the temperature dependence of magnetization, a behavior that is typical of ferromagnets was observed. With a decrease in temperature from 335 K to 4 K, this behavior is replaced by ambiguous hysteresis behavior. The data obtained can be explained by a combination of states of the spin and strain-glass. Studies of iron-containing alloys should be continued since strong superelasticity is of great interest for the construction of superstructures that are resistant to extreme loads.

  • фазовый переход
  • эффект памяти формы
  • сверхупругость
  • деформационное стекло
  • спиновое стекло
  • Fe-Ni-Co-Al-Ta-B
  • сверхустойчивые конструкции
  • phase transition
  • shape memory effect
  • superelasticity
  • strain glass
  • spin glass
  • superstructures
Аннотация (на русском)

Исследование структуры и физических свойств сплавов семейства Fe-Ni-Co-Al

Методами индукционной и дуговой плавки с последующим гомогенизирующим отжигом и закалкой изготовлены слитки сплавов систем Fe-Ni-Co-Al и Fe-Ni-Co-Al-Ta-B, затем электрорезкой и прокаткой изготовлены пластины сплавов и исследованы кристаллографическая структура методом рентгеновской дифракции, а также термомеханические и магнитные свойства. Показан эффект сверхупругости при температуре ниже 330 К. При измерении температурных зависимостей намагниченности обнаружен типичный для ферромагнетиков ход, который при понижении температуры от 335 К до 4 К сменяется неоднозначным гистерезисным поведением. Полученные данные можно объяснить комбинацией состояний «спинового» и «деформационного стекла». Исследования железосодержащих сплавов должны быть продолжены, представляют большой интерес для создания сверхустойчивых к экстремальным нагрузкам конструкций. Recently, it has been proved that the addition of Ta and B as quinary elements to the quaternary Fe-Ni-Co-Al alloy alters the thermoelastic martensitic transformation and also leads to "giant" superelasticity of up to 13.5% in the Fe40.95Ni28Co17Al11.5Ta2.5B0.05 alloy. This is significantly larger than the best binary Ti-Ni shape memory alloy. In addition, the iron-based shape memory alloy is 50% stronger than titanium nickelide (YS =1 GPa). The ingots of alloys of Fe-Ni-Co-Al and Fe-Ni-Co-Al-Ta-B were produced by induction melting/ arc melting technique followed by homogenization annealing and quenching. Then the alloy ingots cut by electro-discharge machining were further subjected to rolling. The crystal structure (by XRD) and thermomechanical and magnetic properties were studied. The alloy exhibits superelasticity at a temperature lower than 330 K. While measuring the temperature dependence of magnetization, a behavior that is typical of ferromagnets was observed. With a decrease in temperature from 335 K to 4 K, this behavior is replaced by ambiguous hysteresis behavior. The data obtained can be explained by a combination of states of the spin and strain-glass. Studies of iron-containing alloys should be continued since strong superelasticity is of great interest for the construction of superstructures that are resistant to extreme loads.

For citation

Koledov V.V., Dilmieva E.T., Kalashnikov V.S., Kamantsev A.P., Mashirov A.V., Gratovski S.V. Fon, Shavrov V.G., Koshkidko I.S., Koshelev A.V., Taskaev S.V., Sampat V., Musabirov I.I., Chung F.V., Grechishkin R.M. Исследование структуры и физических свойств сплавов семейства Fe-Ni-Co-Al // Journal of Radio Electronics. – 2018. – No. 7. https://doi.org/10.30898/1684-1719.2018.7.8

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