Topological properties of single crystals of solid solution (Cd1-xZnx)3As2 composition X = 0.093
Abstract
The value of the cyclotron mass is determined in single crystals of a solid solution (Cd0.907Zn0.093)3As2 according to the results of a study of Shubnikov-de Haase oscillations in a transverse magnetic field. We compared the Shubnikov and Hall parameters of charge carriers. We have found a weak dependence of the cyclotron mass on the magnetic field. The parameters of charge carrier dynamics, such as concentration, Fermi wave vector, charge carrier relaxation time, velocity of charge carriers on the Fermi surface, and average free path of charge carriers were determined. We have determined the value of the Dingle temperature TD = 21.2 K. We have established that the dependence of the cyclotron mass on the Fermi wave vector kF , obtained from experimentally observed Shubnikov-de Haase oscillations, agrees well with the linear dependence predicted by the theory. The dependence of the cyclotron mass on the Fermi wave vector kF and the appearance of the Landau fan diagram indicate the presence of Dirac fermions with near-zero effective mass in single crystals (Cd0.907Zn0.093)3As2.
- Shubnikov-de Haase effect
- Dirac fermions
- zinc arsenide
- cadmium arsenide
Аннотация (на русском)
Топологические свойства монокристаллов твердого раствора (Cd1-xZnx)3As2, X = 0.093
В монокристаллах твёрдого раствора (Cd0.907Zn0.093)3As2 из осцилляции Шубникова-де Гааза в поперечном магнитном поле определена циклотронная масса, проведено сравнение шубниковских и холловских параметров носителей заряда. Наблюдалась линейная зависимость циклотронной массы от магнитного поля. Были определены параметры динамики носителей заряда, такие как концентрация, волновой вектор Ферми, время релаксации носителей заряда, скорость носителей заряда на поверхности Ферми, средняя длина свободного пробега носителей заряда. Определено значение температуры Дингля TD = 21.2 К. Зависимость циклотронной массы, экспериментально наблюдаемой по осцилляциям Шубникова-де Гааза, от волнового вектора Ферми хорошо согласуется с предсказанной теорией линейной зависимостью и совместно с видом веерной диаграммы Ландау указывает на присутствие в монокристаллах (Cd0.907Zn0.093)3As2 фермионов Дирака с околонулевой эффективной массой.
For citation
Zakhvalinskii V.S., Borisenko A.V., Mashirov A.V., Kochura A.V., Sobolev V.V. Topological properties of single crystals of solid solution (Cd1-xZnx)3As2 composition X = 0.093 // Journal of Radio Electronics. – 2025. – No. 4. https://doi.org/10.30898/1684-1719.2025.4.14
References
- Wieder B. J. et al. Topological materials discovery from crystal symmetry //Nature Reviews Materials. - 2022. - Т. 7. - №. 3. - С. 196-216. https://doi.org/10.1038/s41578-021-00380-2
- Crassee I. et al. 3D Dirac semimetal Cd 3 As 2: A review of material properties //Physical Review Materials. - 2018. - Т. 2. - №. 12. - С. 120302. https://doi.org/10.1103/PhysRevMaterials.2.120302
- Ali M. N. et al. The crystal and electronic structures of Cd3As2, the three-dimensional electronic analogue of graphene //Inorganic chemistry. - 2014. - Т. 53. - №. 8. - С. 4062-4067. https://doi.org/10.1021/ic403163d
- Neupane M. et al. Observation of a three-dimensional topological Dirac semimetal phase in high-mobility Cd3As2 //Nature communications. - 2014. - Т. 5. - №. 1. - С. 3786. https://doi.org/10.1038/ncomms2191
- Borisenko S. et al. Experimental realization of a three-dimensional Dirac semimetal //Physical review letters. - 2014. - Т. 113. - №. 2. - С. 027603. https://doi.org/10.1103/PhysRevLett.113.027603
- Mitra A. et al. Constraints on proximity-induced ferromagnetism in a Dirac semimetal (Cd 3 As 2)/ferromagnetic semiconductor (Ga 1- x Mn x Sb) heterostructure //Physical Review Materials. - 2023. - Т. 7. - №. 9. - С. 094201. https://doi.org/10.1103/PhysRevMaterials.7.094201
- Liang T. et al. Ultrahigh mobility and giant magnetoresistance in the Dirac semimetal Cd 3 As 2 //Nature materials. - 2015. - Т. 14. - №. 3. - С. 280-284. https://doi.org/10.1038/nmat4143
- Singh A. et al. Ultrahigh Carrier Mobility in Cd3As2 Nanowires //physica status solidi (RRL)-Rapid Research Letters. - 2023. - Т. 17. - №. 2. - С. 2200365. https://doi.org/10.1002/pssr.202200365
- Rice A. D. et al. High mobility Cd3As2 (112) on GaAs (001) substrates grown via molecular beam epitaxy //ACS Applied Electronic Materials. - 2022. - Т. 4. - №. 2. - С. 729-734. https://doi.org/10.1021/acsaelm.1c01126
- Jeon S. et al. Landau quantization and quasiparticle interference in the three-dimensional Dirac semimetal Cd3As2 //Nature materials. - 2014. - Т. 13. - №. 9. - С. 851-856. https://doi.org/10.1038/nmat4023
- Nelson J. N. et al. Direct link between disorder and magnetoresistance in topological semimetals //Physical Review B. - 2023. - Т. 107. - №. 22. - С. L220206. https://doi.org/10.1103/PhysRevB.107.L220206
- Ouyang W. et al. Extraordinary Thermoelectric Properties of Topological Surface States in Quantum-Confined Cd3As2 Thin Films //Advanced Materials. - 2024. - Т. 36. - №. 28. - С. 2311644. https://doi.org/10.1002/adma.202311644
- Akrap A. et al. Magneto-optical signature of massless Kane electrons in Cd 3 As 2 //Physical review letters. - 2016. - Т. 117. - №. 13. - С. 136401. https://doi.org/10.1103/PhysRevLett.117.136401
- Chorsi H. T. et al. Widely tunable optical and thermal properties of Dirac semimetal Cd3As2 //Advanced Optical Materials. - 2020. - Т. 8. - №. 8. - С. 1901192. https://doi.org/10.1002/adom.201901192
- Gao J. et al. Surface reconstruction, oxidation mechanism, and stability of Cd3As2 //Advanced Functional Materials. - 2019. - Т. 29. - №. 26. - С. 1900965. https://doi.org/10.1002/adfm.201900965
- Ivanov V. et al. Absence of backscattering in Fermi-arc mediated conductivity of the topological Dirac semimetal Cd 3 As 2 //Physical Review B. - 2024. - Т. 109. - №. 19. - С. 195139. https://doi.org/10.1103/PhysRevB.109.195139
- Rancati A. et al. Impurity-induced topological phase transitions in Cd 3 As 2 and Na 3 Bi Dirac semimetals //Physical Review B. - 2020. - Т. 102. - №. 19. - С. 195110. https://doi.org/10.1103/PhysRevB.102.195110
- Lygo A. C. et al. Two-dimensional topological insulator state in cadmium arsenide thin films //Physical Review Letters. - 2023. - Т. 130. - №. 4. - С. 046201. https://doi.org/10.1103/PhysRevLett.130.046201
- Galeeva A. V. et al. Electron energy relaxation under terahertz excitation in (Cd1- xZnx) 3As2 Dirac semimetals //Beilstein Journal of Nanotechnology. - 2017. - Т. 8. - №. 1. - С. 167-171. https://doi.org/10.3762/bjnano.8.17
- Singh M. et al. Topological nature of large bulk band gap materials Sr3Bi2 and Ca3Bi2 //Physica Scripta. - 2023. - Т. 98. - №. 3. - С. 035813. https://doi.org/10.1088/1402-4896/acb7b3
- Zhang X. et al. Three-dimensional Dirac semimetal (Cd1- x Zn x) 3As2/Sb2Se3 back-to-back heterojunction for fast-response broadband photodetector with ultrahigh signal-to-noise ratio //Science China Materials. - 2023. - Т. 66. - №. 4. - С. 1484-1493. https://doi.org/10.1007/s40843-022-2270-1
- Brooks C., Lany S. Heterostructural alloy phase diagram for (Cd 1- x Zn x) 3 As 2 //Physical Review Materials. - 2024. - Т. 8. - №. 6. - С. L061201. https://doi.org/10.1103/PhysRevMaterials.8.L061201
- Zakhvalinskii V. et al. Two-Dimensional Surface Topological Nanolayers and Dirac Fermions in Single Crystals of the Diluted Magnetic Semiconductor (Cd1- x- y Zn x Mn y) 3As2 (x+ y= 0.3) //Crystals. - 2020. - Т. 10. - №. 11. - С. 988. https://doi.org/10.3390/cryst10110988
- Zakhvalinskii V. S. et al. Transport evidence of mass-less Dirac fermions in (Cd1- x- yZnxMny) 3As2 (x+ y= 0.4) //Materials Research Express. - 2020. - Т. 7. - №. 1. https://doi.org/10.1088/2053-1591/ab688b
- Novoselov K. S. et al. Two-dimensional gas of massless Dirac fermions in graphene //nature. - 2005. - Т. 438. - №. 7065. - С. 197-200. https://doi.org/10.1038/nature04233
- Lahoud E. et al. Evolution of the Fermi surface of a doped topological insulator with carrier concentration //Physical Review B-Condensed Matter and Materials Physics. - 2013. - Т. 88. - №. 19. - С. 195107. https://doi.org/10.1103/PhysRevB.88.195107
- Lawson B. J. et al. Quantum oscillations in Cu x Bi 2 Se 3 in high magnetic fields //Physical Review B. - 2014. - Т. 90. - №. 19. - С. 195141. https://doi.org/10.1103/PhysRevB.90.195141
- Kraus W., Nolze G. Windows version of PowderCell 1.0, a program for manipulation of crystal structures and calculation of the corresponding powder diffraction patterns //J. Appl. Crystallogr. - 1996. - Т. 29. - С. 301. https://doi.org/10.1107/S0021889895014920
- Arushanov E. K. Crystal growth and characterization of II3V2 compounds //Progress in crystal growth and characterization. - 1980. - Т. 3. - №. 2-3. - С. 211-255. https://doi.org/10.1016/0146-3535(80)90020-9
- Pietraszko A., Łukaszewicz K. Thermal expansion and phase transitions of Cd3As2 and Zn3As2 //physica status solidi (a). - 1973. - Т. 18. - №. 2. - С. 723-730. https://doi.org/10.1002/pssa.2210180234
- Маренкин С. Ф., Трухан В. М. Фосфиды, арсениды цинка и кадмия //Минск: Вараскин. - 2010.
- Риль А. И. и др. ФАЗОВЫЕ РАВНОВЕСИЯ В ТРОЙНОЙ СИСТЕМЕ CdAs 2-Cd 3 As 2-MnAs //Журнал неорганической химии. - 2017. - Т. 62. - №. 7. - С. 977-987. https://doi.org/10.7868/S0044457X17070200
- Zakhvalinskii V. S. et al. Linear dispersion of Dirac fermions in (Cd1-x-yZnxMny) 3As2, х+ y= 0.2, у= 0.02, 0.04, 0.06, 0.08 solid solutions //Physica Scripta. - 2021. - Т. 96. - №. 12. - С. 125856. https://doi.org/10.1088/1402-4896/ac3873
- Marenkin S. F. et al. Formation of the α''-phase and study of the solubility of Mn in Cd3As2 //Journal of Alloys and Compounds. - 2022. - Т. 892. - С. 162082. https://doi.org/10.1016/j.jallcom.2021.162082
- Allmann R., Hinek R. The introduction of structure types into the Inorganic Crystal Structure Database ICSD //Foundations of Crystallography. - 2007. - Т. 63. - №. 5. - С. 412-417. http://doi.org/10.1107/S0108767307038081
- Dean J. A. Lange's handbook of chemistry. - 1999.
- Ivanov O. et al. Asymmetry and parity violation in magnetoresistance of magnetic diluted Dirac-Weyl semimetal (Cd0. 6Zn0. 36Mn0. 04) 3As2 //physica status solidi (RRL)-Rapid Research Letters. - 2018. - Т. 12. - №. 12. - С. 1800386. https://doi.org/10.1002/pssr.201800386
- Li C. Z. et al. Two-carrier transport induced Hall anomaly and large tunable magnetoresistance in Dirac semimetal Cd3As2 nanoplates //ACS nano. - 2016. - Т. 10. - №. 6. - С. 6020-6028. https://doi.org/10.1021/acsnano.6b01568
- Chen Y. L. et al. Massive Dirac fermion on the surface of a magnetically doped topological insulator //Science. - 2010. - Т. 329. - №. 5992. - С. 659-662. https://doi.org/10.1126/science.1189924
- Шикин А. М. Природа открытия и модификации дираковской щели в аксионном антиферромагнитном топологическом изоляторе MnBi _2 Te _4 //Физика твердого тела. - 2020. - Т. 62. - №. 8. - С. 1293-1301. https://doi.org/10.21883/FTT.2020.08.49617.068
- Zhao Y. et al. Anisotropic Fermi surface and quantum limit transport in high mobility three-dimensional Dirac semimetal Cd 3 As 2 //Physical Review X. - 2015. - Т. 5. - №. 3. - С. 031037. https://doi.org/10.1103/PhysRevX.5.031037
- Guo S. T. et al. Large transverse Hall-like signal in topological Dirac semimetal Cd3As2 //Scientific reports. - 2016. - Т. 6. - №. 1. - С. 27487. https://doi.org/10.1038/srep27487
- Pariari A. et al. Tuning the scattering mechanism in the three-dimensional Dirac semimetal Cd 3 As 2 //Physical Review B. - 2016. - Т. 94. - №. 16. - С. 165139. https://doi.org/10.1103/PhysRevB.94.165139
- Цидильковский И. М. Зонная структура полупроводников. - Наука. Гл. ред. физ.-мат. лит., 1978.
- Zakhvalinskii V. S. et al. Anomalous cyclotron mass dependence on the magnetic field and Berry's phase in (Cd1- x- yZnxMny) 3As2 solid solutions //Journal of Physics: Condensed Matter. - 2017. - Т. 29. - №. 45. - С. 455701. https://doi.org/10.1088/1361-648X/aa8bdb
- Laiho R. et al. Shubnikov-de Haas effect in thermally annealed (Cd1- x- yZnxMny) 3As2 //Journal of Physics and Chemistry of Solids. - 1997. - Т. 58. - №. 5. - С. 717-724. https://doi.org/10.1016/S0022-3697(96)00194-1
- Laiho R. et al. Shubnikov-de Haas Effect in (Cd1- x- yZnxMny) 3As2 under Pressure //physica status solidi (b). - 1996. - Т. 198. - №. 1. - С. 135-141. https://doi.org/10.1002/pssb.2221980119
- Petrushevsky M. et al. Probing the surface states in Bi 2 Se 3 using the Shubnikov-de Haas effect //Physical Review B-Condensed Matter and Materials Physics. - 2012. - Т. 86. - №. 4. - С. 045131. https://doi.org/10.1103/PhysRevB.86.045131
- Lawson B. J., Hor Y. S., Li L. Quantum oscillations in the topological superconductor candidate Cu 0.25 Bi 2 Se 3 //Physical Review Letters. - 2012. - Т. 109. - №. 22. - С. 226406. https://doi.org/10.1103/PhysRevLett.109.226406
- Murakawa H. et al. Detection of Berry's phase in a bulk Rashba semiconductor //Science. - 2013. - Т. 342. - №. 6165. - С. 1490-1493. https://doi.org/10.1126/science.1242247.
- Xiang Z. J. et al. Angular-dependent phase factor of Shubnikov-de Haas oscillations in the Dirac semimetal Cd 3 As 2 //Physical review letters. - 2015. - Т. 115. - №. 22. - С. 226401. http://doi.org/10.1103/PhysRevLett.115.226401